I love your outside entertaining area. It does need a color that would complement but give the area a focal point. I like the darker red,orange colors you may find in natural. You could dress up the table with accessories and place cushions in a complimentary color on the benches. Colored potting containers would also bring it all together. I like the uplighting here in the photo you could place along the back fence to add drama. Your area reminds me of Modern mediterranean landscaping.

I like @kelly's idea of picking a lovely fresh color of paint for the door. You can then bring it down onto the stair risers. Either a solid color to match the front door, or go wild and add some decorative elements to the risers with stencils. Or think of staining the door a great color and coordinate the stair railings and risers. I have an idea book put together for just such project that might spark some ideas for you. http://www.houzz.com/ideabooks/16700983/thumbs/Kathryn-Delany-s-Decorative-Stair-Risers

Blue gray window frames match the funky roof. The cedar is diametrically opposite on the color wheel as a orange tone. Usually the browner grays (sort of the light shade now on the stucco) do better with cedar to say modern, but since you have the blue gray, allow me to suggest that you just go as dark gray as you can - nearly charcoal on all the weatherboard. If you are in a high heat area (palms might or might not be - that might be the ocean on the horizon which might me an onshore breeze all the time) then you want a white. Not a blue-white but a warm white - bm maritime white is a good choice. With the cedar and the two blue-blue-gray elements, you need neutral without tone.

Thanks for all the great ideas everyone and sorry I didn't explain the polycarbonate a bit better :) This is along the lines of what we'll be using... http://www.psp.co.nz/building-brands/corrugated-sheeting/suntuf-polycarbonate The area is an absolute sun trap and we're hoping to use it as an extension to our living space, especially on rainy days! I've just sent my husband out to get a few pots of different stains for is to try - darkest brown (cedar) and a lighter brown (rustic oak) both by Cabots + the black we already have. Hopefully we can decide between one of those! I probably should have mentioned we will have black aluminium pool fencing running along the top of the second retaining wall - so the real question is do we keep everything black (pool fencing, horizontal fence, retaining walls and pergola) or do we go with a dark (or even light) brown for the pergola and retaining walls.... We just keep going around in circles at the moment. Decisions, decisions! Thanks again :)