Deep gray and all the other accents in silvery old wood and cream. This will add drama, allow the other elements to bring ion light and set off the concrete wall as a true feature. If you want light instead of drama, then go for a very pale beige stone. It will echo stone colours in both the concrete and rocks...

based on the drawing, the wall where the bed is. HOWEVER, you mentioned that this drawing is not a true depiction of the furniture you will use and the wallpaper. if that is the case, i think the wall paper can work on either wall, it all depends on how busy this wallpaper is and how "plain" the bed is. if you go with a busy wallpaper behind the bed, you may want to keep your bed and bedding on the minimal side so that there is a good visual balance to the overall composition. if you go with snazzier bedroom furniture, then a busy wallpaper may be a bit much and you may want to put it on the other wall or use a textural option to serve as the bed's background rather then another focal point.

this room has one large window which takes up most of the wall facing north.quite a bright bedroom. would it look funny having a green, black and 2white walls? I just want to tie the black furniture in with a black fixture somehow. maybe you have other suggestion?

Sophisticated start. You could go with black and white photography, architectural pieces, art pieces- anything you love on the wall. Then, add pillows in the colors of the art work. If you want to stay more monochromatic, think in terms of textural interest, such as a shag area rug, pillows with seam detailing, etc.