They may have used small dowl rods or biscuits to join the chair. Which usually means a void/rebate is created and then a proud piece glued into the void. (Think male/female sockets etc). So you may be able to gently tap (rubber mallet, not metal hammer) to get the pieces apart. Use fabric or thick wadding or sponge to protect your timber when you whack it.

Hi Anna, I used leather for the recovering. This made things easier as it stretches quite a bit and is very forgiving. I used one piece for the backs. I stapled one end of the fabric to the bottom edge of the back, then wrapped it around back to just over the staples, folded under the raw edge and used upholstery nails to secure.

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You are correct the place does and always will look a bit sparse when you only have blinds. The question with curtains is sometimes dependant on what climate you live in and I am not sure where you are so I am going to say. If you need curtains for heat go for a quality curtain to the floor with a fabric that is not stiff (as I discovered I now own after buying curtains off line for my spare rooms). The expensive curtains I brought for my living room have a softer texture and hang so much nicer. As I need Curtains / Roman blinds for heat I have backing fabric etc on the expensive made to measure ones, where as the cheaper ones are just thermals. If you only want to add a curtain for looks and do not require it for heat I would recommend going with a lovely sheer / half see through fabric that drapes really well, this will add a point of interest and you can colour match or add a loved colour to a bare - white on white - cream on cream - colour scheme.