I think this gray faux wood tile will look very nice with brown carpet. It also will look wonderful in an all white kitchen!

Not sure what you mean by bench but painting the cupboards white sounds like a great solution to the all green kitchen. You could even break up some of the green tiles with floor mats as well. Best of luck.

Paint your house and ceiling first. You are probably asking for trouble if you put the floors down only to paint over the top of them. If you can, remove the tiles in the kitchen and paint just behind the line of the splashback too. Once painting is done replace kitchen benchtop then splashback. I would call the bathroom its own job and do it individually, unless you only need to paint the ceiling and if a tiler doesn't need to be brought in for anything else in the house? A lot of bathrooms now are getting tiled from floor to the ceiling if this is the case, paint the ceiling first, then tile. If walls need to be painted, it wouldn't really matter if you did them first or last, though if you did it first expect to do some touch-ups. I guess if you really wanted, you could do the first coat before tiles then second after... I don't exactly like stopping and starting painting, so I would do the walls (if they needed to be done) in one hit, after its been tiled. Well that's the order in which I would do everything... Really, for what you're asking, the painting could be done at anytime, but to make life easy on yourself, I would definitely recommend doing it before the floor.

I wouldn't do skirtings . I'd do the floor tile for '1 tile' up the wall ( assume they are 200 x 200 or 300 x 300 -- cut them if 400 or 600 ) . Personally , I'd probably even do the 'silver' tiled areas in that 1 height darker tile too , as it would make the whole room look more 'level' , but thats up to you and your tiler .