They may have used small dowl rods or biscuits to join the chair. Which usually means a void/rebate is created and then a proud piece glued into the void. (Think male/female sockets etc). So you may be able to gently tap (rubber mallet, not metal hammer) to get the pieces apart. Use fabric or thick wadding or sponge to protect your timber when you whack it.

Beautiful table. I don't particularly like the metal/cane chairs. Too 'light' in appearance. Do you use the chairs by the window? I think they are too close to the table and they are too big in comparison. Could be the angle of the photos though, may look different in real life. I don't think your ceiling is too low to hang a pendant above the table. How do you change the table position? If you only turn it around, you can still keep it centered under a light. If you move it to the wall it's another story of course. The two paintings above the console should be hung lower and I prefer them on one level. You can add table lamps on the console and a floor lamp in the corner between the windows. If you use the two chairs, I would add a table in between and angle the chairs a bit. I'll see if I can find you other dining chair options.

The chairs are a good match. Leather is probably best, great for kids' spills and accidents, but any fabric will do. Not sure on purple with green - those two colours together clash a bit for me. The green kitchen looks great, and I'm a fan of dark wood. The only thing throwing it off at the moment is the yellowish coloured walls. If they were repainted a soft white, this would make the green and the dark wood really pop, giving you a fresh and sophisticated, calm look which I think would work well. You could then upholster in a green to match the kitchen which would look appealing. Finish it off by some fresh white flowers as accents in the room to draw the eye and you've got a beautifully transformed space with a fabulous feature dining area :)

Congratulations on your new home! Now, go cancel that order! Just kidding. Kind of... I really do think, after reading your posts, that you will be happier with the grey couches. Personally, black couches in general seem very bachelor pad (ish). That said, I know there are gorgeous black leather couches available. For a super modern industrial place, maybe. But beach, or that kind of vibe? I am not sure how you would pull that off over the years. Grey or tan (neither are my own favorite decorating colors, but still) would be oh so much better as a neutral for pulling in different color palettes with pillows and art, etc. if you decide to change up through the years... black might make you feel stuck. After reading through what I have written it seems a bit funny, as black is my personal neutral in clothing, jewelry and the like. But as I look around my home there is no black to be seen. Hmmm. In any event, follow your own intuition here, and don't feel like you have to fill the space before your home is even completed. Especially if you are having second thoughts. And remember, this is supposed to be fun for you! When in doubt, leave it out! At least for the time being.