You can put the TV over the fireplace, not the best situation but the way the room lays out it is the only logical place to put it. If you could you should add one additional layer on your mantel that could extend it out another 4" to deflect the radiant coming from the fireplace. I would also mount it on a slimline mounting bracket and have the bottom of the TV no further than 4" above the mantle. Ideally you want the TV to be in as straight a line as possible with your eyes. You don't want to look up too high at the TV, it's like being at a sports bar. Also if you can snake up the power and the HDMI from the cable there is a box they make that has both in one so it makes for a very clean installation.

For the fireplace inserts go ahead and do the green order a second set of panels that you store that are more neutral. In 10 years or five years you may not like the green anymore. It's possible you won't have access to different colored panels at that time. As for the color I like the ideas of going into those silvers it would coordinate very well with your blue couch and it will pull the blues out of the curtain panels. For the wall coloring use the warm golden color in the drape. There is one piece of the flower that has this color and it will balance the weight of a dark couch. If your room is small don't go too dark in this color. You could use it on the main wall and pick two shades lighter on the other three walls.

Is that a window in center above the hearth? Is rock just a facade? Looks like you have a mixture of furniture styles. Windows look more of the modern style while drapes are traditional. I would say pick one style and go with that. From the windows I'd be leaning modern/ contemporary. If the rock is just stuck on wall take it off. Replace with horizontal wood planks stained same as your door casings. No mantle. If that is a window I would either have a stained glass insert made (again using modern lines) or do a faux stain glass painting treatment to add some visual interest.

This made me laugh: http://www.theguardian.com/environment/2016/jun/09/seagull-turns-orange-after-falling-into-vat-of-chicken-tikka-masala I couldn't copy the picture, but it's hilarious.