You can put the TV over the fireplace, not the best situation but the way the room lays out it is the only logical place to put it. If you could you should add one additional layer on your mantel that could extend it out another 4" to deflect the radiant coming from the fireplace. I would also mount it on a slimline mounting bracket and have the bottom of the TV no further than 4" above the mantle. Ideally you want the TV to be in as straight a line as possible with your eyes. You don't want to look up too high at the TV, it's like being at a sports bar. Also if you can snake up the power and the HDMI from the cable there is a box they make that has both in one so it makes for a very clean installation.

If you use masonry paint, we could head in a warm greige direction for all of it - not so yellow . .. something that can give you a bit more contrast against the white windows and trim - even 40 does a lot for us . . . what about a blue green gray? You will get a coastal / mod vibe and it will relate to the farmhouse look .. .above bm silver mink http://www.benjaminmoore.com/en-us/paint-color/silvermink and below . . . gilbraltar cliffs . . http://www.benjaminmoore.com/en-us/paint-color/gibraltarcliffs Shingle look siding on the side dormers would be neat to get that cottage mod. . . you can stick with yellow but I don't think it complements the roof tone. With the blue-green grays, the white windows and trim will really pop beautifully. . . You can also go more neutral with a warm gray - greige . . . here's the siding tone http://www.benjaminmoore.com/en-us/paint-color/capemaycobblestone paired with this for brick - http://www.benjaminmoore.com/en-us/paint-color/graystone potential future red windows . . .aluminum pits over time, so if you have just one side you want to try, you don't have to powder coat, you can take a small brush and just do them by hand with latex paint if they are 10 yrs old or more. . . one advantage to gray . . future see [houzz=]

Bring the window down to meet the cupboard. Really lefty47 was right about not drawing attention to it. It is a source of light ,,, so no need to clutter it up. But if you took the colour out and painted the top of the cupbard to match the wall it ceases to draw attention to itself. Just because it is a horizontal space does not meant it needs something put on it. Note- With the cupboard being white, it also draws attention to itself … perhaps take that to the wall colour too and lift the pendant a smidge. So your pendant is the feature there. The cupboard … do yo need it? One way to remove what you are calling dead space is to get rid of the cupboard.

My ex-husband and I had an issue with a large window that looked out over a sidewalk where people were constantly walking by and looking directly into our living room. We solved the problem by using window film that was one-way so we could see out but it was like a mirror if anyone tried to look in. There are other varieties as well. We still got all the sunshine and light but didn't need to worry about whether or not the neighbors could see me watching tv in my nightie on a sick day...It also meant the door to door salesmen couldn't look in and see that I was home when I didn't answer the door. http://www.gilafilms.com/en/privacy-window-film.aspx#.VOuUBS5vksQ